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Showing posts with label ceramic stains. Show all posts
Showing posts with label ceramic stains. Show all posts

Thursday, 19 June 2014

Pottery Materials-Potters You've Never Had it So Good!

Sources of materials

Materials dug from the ground have been the source of pottery making for thousands of years. However early potters relied heavily on local materials, especially the clays and sands. This was certainly the case in my beloved Staffordshire, England where local marl clays formed the major source of clay for early industrial potters.

Borax granules
Today materials are shipped around the world to areas of high industrial scale ceramic manufacture. For example the high quality white china clays from the south of England are often shipped to Asia to make the finest bone china and porcelain bodies. Similarly borax and boron minerals from Turkey and the USA are used in Europe to make glazes and frits for tile, tableware and sanitary ware manufacture.

However it is not just the source of available materials but also the quality and consistency that has helped modern potters and potteries to improve their quality, designs and efficiency.

Materials for body making

Body materials
The main materials used to produce a clay body are silica or quartz, felspar, and clays. These materials come in various purities, particle sizes, and qualities. To produce the finest white bodies, high purity low iron materials are used and these materials are sourced locally where available. However most areas of pottery manufacture do not have the required purity or consistency required from all their local suppliers and are therefore forced to consider other supplies. It is the consistency in purity, and control of of material properties that has made a significant difference to large scale pottery manufacturers. They can automate processes and improve efficiency to reduce costs. Materials are now stardardised to fit processing routes. For example 30 mesh and 200 mesh materials are common in the UK. These improvements in materials for industrial scale customers also has a knock on benefit for craft, hobby and studio potters who can also purchase these same materials from distributors and use them with greater confidence.

Materials for glaze making

Frit granules
Like body the main materials used for glaze making are silica, china clay, and felspar. However frits (fused glass fragments) and other minerals such as limestone, dolomite, wollastonite, zircon are often added to control the fired properties of the glaze. Expensive technical grade chemicals such as zinc oxide, barium carbonate,and boric acid are also used in small quantities in the glaze or frit to meet the most demanding glaze requirements. However it is in the use of boron products where industrial scale and craft scale differ the most. Large scale glaze manufacturers predominantly use frits as a source of boron, where craft glaze makers use boron products such as Gerstley borate. The benefits of using frits for industrial scale glaze manufacture are far reaching. The recipe of the glaze is designed to be lead free and often fine tuned to give the widest firing range and technical performance. Control of glaze slip properties, glaze application, and firing properties are of paramount importance especially in automated plants which are not suited to the use of borates in glaze. Slip control of the glaze involves controlling both the solids content of the slurry, the viscosity (fluidity) and the drying time by means of chemical additives.

This differentiation in supply is a benefit to craft and hobby potters who can choose a from a wide range of frits or borates depending on their scale of operation or cost needs. .

Materials for decoration

A whole range of  methods are now available for decoration of pottery. When colour was introduced to pottery in early years it was in the form of naturally occurring coloured minerals usually high in iron. Consequently the colour range was restricted to brown- red to grey blue in colour depending on the firing condition. However with the development of pigments from the eighteenth century many more colours became available with Chinese blue colour on white glaze becoming very popular.                                      
range of onglaze decorating colours


Today a full range of stable mixable ceramic colours are available ranging from bright yellow to blue to red. Together with a wider range of decorating techniques the modern potter now has the opportunity to design truly unique ware that is also repeatable.

Range of ceramic stains


To put this into perspective an anology might be to compare Fords "you can have it in any colour as long as its black" to the current range of colours and effects used to paint modern vehicles.

In a similar way to body and glaze materials, decorating colours such as onglaze have become standardised and more consistent in both their application and firing. Colours have been developed without lead and are available in the best medium (liquid) to allow optimum application whether that is hand painting, machine banding or screen printing. Introduction of digital printing has allowed digital images to be translated from computer to ware using ink jet decals or even direct printing in a similar fashion to paper printing. For the hand made purists in pottery computer support to design has not always been welcomed but it has extended the range of design to new levels.

In the future design will be pushed even further by 3D printing which is in its infancy in the pottery industry.

Summary

Clearly material technology and control in the pottery industry has progressed almost unnoticed since the early eighteenth century pottery manufacture. However it has progressed and the development of more consistent, environmentally friendly colours together with a wider colour palette has been of great benefit to modern potters, large and small..  The advent of digital printing in recent years and the potential of 3D printing is set to revolutionise the industry further creating even more design possibilities.

Yes Potters it is true! You've never had it so good!
Comments welcomed?

Happy Potting
The Potters Friend

More information and other technical articles on pottery and ceramics can be found at my website The Potters Friend.

Go now to sign up for my free newsletter.



Wednesday, 23 April 2014

How to Make Coloured Pottery

The Appeal of Colour

Copper Ruby glaze
The addition of colour to pottery adds so much to its appeal. Whilst white pottery can emphasise the distinctive form of a piece it is often colour which catches the eye! Colour is often associated with a mood or feeling and this varies between cultures and countries. For example red is a very emotive colour and can mean anything from love and romance to danger and fire! Choosing the right colour to make or decorate your pottery however is a matter of personal choice and allows for much creativity and freedom of expression.

Colour can be added to pottery in many ways including body colour, underglaze, inglaze, onglaze and also as a component of the glaze itself.


In this article I will try to review the two main types of ceramic pigment ( raw oxide and ceramic stains) available and how they can be used to produce highly decorative pottery.

In the second of my series on glaze I described how to make a white textured stoneware glaze. 
Simply adding inorganic colouring oxides such as Iron Oxide to such a glaze produces colour but not always the desired colour!  Carry on reading to find out why!

Raw Oxides in Coloured Glaze


Top = Oxides in transparent glaze
Bottom = Oxides in opaque glaze
Copper oxide crackle glaze
It is common for raw oxide pigments to be used used in pottery making. Many studio and craft potters prefer to use cobalt oxide, chrome oxide, Iron oxide and copper oxide as colouring pigments.These oxides give blue, green, yellow-brown, and green-blue respectively on firing in or under the glaze. Often the fired colour of the starting oxide is not the same as the original oxide colour e.g. cobalt oxide changes from black to blue on firing in a glaze. However mixing of these oxides in a glaze, gives variable but often aesthetically pleasing artistic effects on firing. It is for this reason, and the lower cost involved that many studio potters often use these materials.

Iron Oxide and cobalt oxide in glazes
In using oxides as pigments It is important to match the pigment type and content to the glaze to achieve the most consistent results. In the example above iron oxide gives a yellow colour when added to a glaze in small percentage (eg 1%) compared to a brown colour in high percentage (eg 15%). In combination iron oxide and cobalt oxide often give grey or a black glaze colour (see example right). The difference in the colour between an opaque and transparent glaze containing the same pigment content is also marked. In the example above the same pigment content is compared in a transparent glaze (top) and an opaque glaze (bottom). A stoneware textured glaze will produce colour tones similar to those of an opaque glaze.


Organic pigments such as those used in paper printing are clearly not suitable and will simply burn away during firing

Ceramic Stains in Coloured Glazes



Top = Ceramic stains in transparent glaze
Bottom = Ceramic stains in opaque glaze

In contrast to raw oxide pigments, ceramic stains have been specially formulated to create a wide range of colour tones in glaze. In their manufacture they have undergone a heat process and a fine grinding process so that they are highly temperature stable and capable of being mixed together to generate intermediate colour tones. This property is highly valued by large scale manufacturers who need consistency of colour tones. However this all comes at a cost compared to raw oxides.

Onglaze and Inglaze Decoration


Pantone Mugs showing onglaze colours
It is common for high quality whitewares such as bone china and porcelain to be decorated with special colours called onglaze (low temperature) or inglaze (high temperature). These colours use a mix of special fluxes and the ceramic stains identified above to create a wide range of intense, durable colours and bond them to the already fired glaze surface.. Whilst a few studio potters try to make their own, they are best supplied by specialist manufacturers to ensure they meet current legislation and perform satisfactorily in use. These colours are often supplied as powders or pre-dispersed in a liquid allowing them to be applied by hand painting or screen printing. This type of colour is very versatile and is often used to make precision decorative decals for water slide application onto pre-glazed pottery. A new development called Digital printing now allows these decals to be personalised and produced in small quantities making it a cost effective method of decoration for craft and hobby use.

Summary

Clearly there is more to making coloured pottery than is immediately obvious. For those who want consistent colour that can be mixed to give intermediate shades then use ceramic stains either as a glaze component or in decoration products such as inglaze or onglaze colours. For those who want unpredictable but aesthetically pleasing results use oxides as a glaze component or under the glaze. Whichever option you choose using colour creatively will only add to the appeal of your pottery.

Happy Potting
The Potters Friend

More information and other technical articles on pottery and ceramics can be found at my website The Potters Friend.

Go now to sign up for my free newsletter.